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Results: 28

Joan Serrano-Plana, Ferran Acuña-Parés, Valeria Dantignana, Williamson N. Oloo, Esther Castillo, Apparao Draksharapu, Christopher J. Whiteoak, Vlad Martin-Diaconescu, Manuel G. Basallote, Josep M. Luis, Lawrence Que, Miquel Costas, Anna Company
Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds
Chem. Eur. J., 2018, 24, 5331-5340
DOI: 10.1002/chem.201704851
Keywords: Oxidation, Reaction mechanisms, Spectroscopy, Density Functional Theory, Computational chemistry

Laia Vicens, Miquel Costas
Biologically inspired oxidation catalysis using metallopeptides
Dalton Trans., 2018, 47, 1755-1763
DOI: 10.1039/C7DT03657D
Keywords: Catalysis, High-valent metal complexes, Oxidation, Supramolecular chemistry, Sustainable Catalysis

Erik Andris, Rafael Navrátil, Juraj Jašík, Mayank Puri, Miquel Costas, Lawrence Que, Jana Roithová
Trapping Iron(III)–Oxo Species at the Boundary of the “Oxo Wall”: Insights into the Nature of the Fe(III)–O Bond
J. Am. Chem. Soc., 2018, 140, 14391-14400
DOI: 10.1021/jacs.8b08950
Keywords: Chemical bonding, High-valent metal complexes, Metalloproteins, Oxidation, Reaction mechanisms

Ruixi Fan, Joan Serrano-Plana, Williamson N. Oloo, Apparao Draksharapu, Estefanía Delgado-Pinar, Anna Company, Vlad Martin-Diaconescu, Margarida Borrell, Julio Lloret-Fillol, Enrique García-España, Yisong Guo, Emile L. Bominaar, Lawrence Que Jr., Miquel Costas, Eckard Münck
Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV–Oxo Intermediate
J. Am. Chem. Soc., 2018, 140, 3916–3928
DOI: 10.1021/jacs.7b11400
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Spectroscopy

Michela Milan, Massimo Bietti, Miquel Costas
Aliphatic C–H Bond Oxidation with Hydrogen Peroxide Catalyzed by Manganese Complexes: Directing Selectivity through Torsional Effects
Org. Lett., 2018, 20, 2720-2723
DOI: 10.1021/acs.orglett.8b00929
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Valeria Dantignana, Michela Milan, Olaf Cussó, Anna Company, Massimo Bietti, Miquel Costas
Chemoselective Aliphatic C–H Bond Oxidation Enabled by Polarity Reversal
ACS Cent. Sci., 2017, 3, 1350–1358
DOI: 10.1021/acscentsci.7b00532
Keywords: Catalysis, Oxidation, Sustainable Catalysis

Giorgio Olivo, Giulio Farinelli, Alessia Barbieri, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Supramolecular Recognition Allows Remote, Site-Selective C−H Oxidation of Methylenic Sites in Linear Amines
Angew. Chem., 2017, 56, 16347
DOI: 10.1002/anie.201709280
Keywords: Catalysis, High-valent metal complexes, Oxidation, Supramolecular chemistry, Sustainable Catalysis

Michela Salamone, Teo Martin, Michela Milan, Miquel Costas, Massimo Bietti
Electronic and Torsional Effects on Hydrogen Atom Transfer from Aliphatic C–H Bonds: A Kinetic Evaluation via Reaction with the Cumyloxyl Radical
J. Org. Chem., 2017, 82, 13542-13549
DOI: 10.1021/acs.joc.7b02654
Keywords: Oxidation

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