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Results: 51

Laia Vicens, Giorgio Olivo, Miquel Costas
Remote Amino Acid Recognition Enables Effective Hydrogen Peroxide Activation at a Manganese Oxidation Catalyst
Angewandte Chemie Intl Edit, 2022, 61, e202114932
DOI: 10.1002/anie.202114932
Keywords: Catalysis, Oxidation, Reaction mechanisms, Supramolecular chemistry, Sustainable Catalysis

Miquel Costas, Anna Company
Oxidative C−F Cleavage in Metalloenzymes and Model Compounds
Euro J of Inorganic Chem, 2022, 2022, ASAP-
DOI: 10.1002/ejic.202100754
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Marco Galeotti, Laia Vicens, Michela Salamone, Miquel Costas, Massimo Bietti
Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp3 )–H Functionalization via Radical and Cationic Intermediates
J. Am. Chem. Soc., 2022, 144, 7391-7401
DOI: 10.1021/jacs.2c01466
Keywords: High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Silvia D’Agostini, Konstantin G. Kottrup, Carla Casadevall, Ilaria Gamba, Valeria Dantignana, Alberto Bucci, Miquel Costas, Julio Lloret-Fillol, Dennis G.H. Hetterscheid
Electrocatalytic Water Oxidation with α-[Fe(mcp)(OTf)2 ] and Analogues
ACS Catal., 2021, 11, 2583-2595
DOI: 10.1021/acscatal.0c05439
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Anja Knorrscheidt, Jordi Soler, Nicole Hünecke, Pascal Püllmann, Marc Garcia-Borràs, and Martin J. Weissenborn
Accessing Chemo- and Regioselective Benzylic and Aromatic Oxidations by Protein Engineering of an Unspecific Peroxygenase
ACS Catal., 2021, [], 7327-7338
DOI: 10.1021/acscatal.1c00847
Keywords: Catalysis, Computational chemistry, Enzyme design, Metalloproteins, Oxidation

Eduard Masferrer-Rius, Margarida Borrell, Martin Lutz, Miquel Costas, RobertusJ.M. Klein Gebbink
Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes
Adv. Synth. Catal., 2021, 363, 3783-3795
DOI: 10.1002/adsc.202001590
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Laia Vicens, Massimo Bietti, Miquel Costas
General Access to Modified α‐Amino Acids by Bioinspired Stereoselective γ‐C‐H Bond Lactonization
Angew. Chem. Int. Ed., 2021, 60, 4740-4746
DOI: 10.1002/anie.202007899
Keywords: Catalysis, High-valent metal complexes, Oxidation, Sustainable Catalysis

Alexander Brinkmeier, KristianE. Dalle, Lorenzo D’Amore, RolandA. Schulz, Sebastian Dechert, Serhiy Demeshko, Marcel Swart, Franc Meyer
Modulation of a μ-1,2-Peroxo Dicopper(II) Intermediate by Strong Interaction with Alkali Metal Ions
J. Am. Chem. Soc., 2021, 143, 17751-17760
DOI: 10.1021/jacs.1c08645
Keywords: Density Functional Theory, Excited states, High-valent metal complexes, Oxidation, Spectroscopy

Margarida Borrell, Sergio Gil-Caballero, Massimo Bietti, Miquel Costas
Site-Selective and Product Chemoselective Aliphatic C–H Bond Hydroxylation of Polyhydroxylated Substrates
ACS Catal., 2020, 10, 4702-4709
DOI: 10.1021/acscatal.9b05423
Keywords: Catalysis, Oxidation

Laia Vicens, Giorgio Olivo, Miquel Costas
Rational Design of Bioinspired Catalysts for Selective Oxidations
ACS Catal., 2020, 10, 8611-8631
DOI: 10.1021/acscatal.0c02073
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

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