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Results: 52

Silvia D’Agostini, Konstantin G. Kottrup, Carla Casadevall, Ilaria Gamba, Valeria Dantignana, Alberto Bucci, Miquel Costas, Julio Lloret-Fillol, Dennis G.H. Hetterscheid
Electrocatalytic Water Oxidation with α-[Fe(mcp)(OTf)2 ] and Analogues
ACS Catal., 2021, 11, 2583-2595
DOI: 10.1021/acscatal.0c05439
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Eduard Masferrer-Rius, Margarida Borrell, Martin Lutz, Miquel Costas, RobertusJ.M. Klein Gebbink
Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes
Adv. Synth. Catal., 2021, 363, 3783-3795
DOI: 10.1002/adsc.202001590
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Laia Vicens, Massimo Bietti, Miquel Costas
General Access to Modified α‐Amino Acids by Bioinspired Stereoselective γ‐C‐H Bond Lactonization
Angew. Chem. Int. Ed., 2021, 60, 4740-4746
DOI: 10.1002/anie.202007899
Keywords: Catalysis, High-valent metal complexes, Oxidation, Sustainable Catalysis

Kallol Ray, Katrin Warm, Alice Paskin, Uwe Kuhlmann, Eckhard Bill, Marcel Swart, Michael Haumann, Holger Dau, Peter Hildebrandt
A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C‐H bond Oxidation Reactions
Angew. Chem. Int. Ed., 2021, 60, 6752-6756
DOI: 10.1002/anie.202015896
Keywords: Catalysis, Computational chemistry, High-valent metal complexes, Spectroscopy

Pau Font, Xavi Ribas
Fundamental basis for implementing oxidant‐free Au(I)/Au(III) catalysis
Eur. J. Inorg. Chem., 2021, 26, 2556-2569
DOI: 10.1002/ejic.202100301
Keywords: Catalysis, Cross-coupling reactions, High-valent metal complexes, Organometallics

Sílvia Escayola, Artur Brotons-Rufes, Naeimeh Bahri-Laleh, Francesco Ragone, Luigi Cavallo, Miquel Solà, Albert Poater
Fluxional bis(phenoxy-imine) Zr and Ti catalysts for polymerization
Theor Chem Acc, 2021, 140, 49
DOI: 10.1007/s00214-021-02747-8
Keywords: Aromaticity, High-valent metal complexes, Organometallics, Reaction mechanisms

Kallol Ray, Katrin Warm, Inés Monte Pérez, Uwe Kuhlmann, Peter Hildebrandt, Erik Farquhar, Marcel Swart
Stable, but still reactive – investigations on the effects of Lewis acid binding on copper nitrene intermediates
Z. anorg. allg. Chem., 2021, 647, 1495-1502
DOI: 10.1002/zaac.202100092
Keywords: Catalysis, Computational chemistry, High-valent metal complexes, Spectroscopy

Laia Vicens, Giorgio Olivo, Miquel Costas
Rational Design of Bioinspired Catalysts for Selective Oxidations
ACS Catal., 2020, 10, 8611-8631
DOI: 10.1021/acscatal.0c02073
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Giorgio Olivo, Giorgio Capocasa, Barbara Ticconi, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Predictable selectivity in remote C‐H Oxidation of steroids via analysis of substrate binding mode
Angew. Chem. Int. Ed., 2020, 59, 12703-12708
DOI: 10.1002/anie.202003078
Keywords: Catalysis, High-valent metal complexes, Oxidation, Predictive Chemistry, Supramolecular chemistry

Lorenzo D’Amore, Leonardo Belpassi, Johannes E. M. N. Klein, Marcel Swart
Spin-resolved charge displacement analysis as an intuitive tool for the evaluation of cPCET and HAT scenarios
Chem. Commun. , 2020, 56, 12146-12149
DOI: 10.1039/d0cc04995f
Keywords: Catalysis, Chemical bonding, High-valent metal complexes, Reaction mechanisms

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