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Results: 44

Mainak Mitra, Alexander Brinkmeier, Yong Li, Margarida Borrell, Arnau Call, Julio Lloret Fillol, MichaelG. Richmond, Miquel Costas, Ebbe Nordlander
An investigation of steric influence on the reactivity of Fe^V (O)(OH) tautomers in stereospecific C–H hydroxylation
Dalton Trans., 2023, [], ASAP-
DOI: 10.1039/D2DT00725H
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Arnau Vicens, Laia Vicens, Giorgio Olivo, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Site-selective methylene C-H oxidation of an alkyl diamine enabled by supramolecular recognition using a bioinspired manganese catalyst
Faraday Discuss., 2023, [], ASAP-
DOI: 10.1039/D2FD00177B
Keywords: Catalysis, Oxidation, Reaction mechanisms, Supramolecular chemistry, Sustainable Catalysis

Valeria Dantignana, M. Carmen Pérez-Segura, Pau Besalú-Sala, Estefanía Delgado-Pinar, Álvaro Martínez-Camarena, Joan Serrano-Plana, Andrea Álvarez-Núñez, CarmenE. Castillo, Enrique García-España, JosepM. Luis, ManuelG. Basallote, Miquel Costas, Anna Company
Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity
Angew Chem Int Ed, 2022, [], ASAP-
DOI: 10.1002/anie.202211361
Keywords: High-valent metal complexes, Oxidation, Reaction mechanisms

Laia Vicens, Giorgio Olivo, Miquel Costas
Remote Amino Acid Recognition Enables Effective Hydrogen Peroxide Activation at a Manganese Oxidation Catalyst
Angewandte Chemie Intl Edit, 2022, 61, e202114932
DOI: 10.1002/anie.202114932
Keywords: Catalysis, Oxidation, Reaction mechanisms, Supramolecular chemistry, Sustainable Catalysis

Johann B. Kasper, Pattama Saisaha, Maurits de Roo, Mitchell J. Groen, Laia Vicens, Margarida Borrell, Johannes W. de Boer, Ronald Hage, Miquel Costas, Wesley R. Browne
A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H₂ O₂ and a Mn(II)/Pyridin‐2‐Carboxylato Catalyst
ChemCatChem, 2022, [], ASAP-
DOI: 10.1002/cctc.202201072
Keywords: Catalysis, Oxidation, Reaction mechanisms, Spectroscopy, Sustainable Catalysis

Miquel Costas, Anna Company
Oxidative C−F Cleavage in Metalloenzymes and Model Compounds
Eur. J. Inorg. Chem., 2022, 2022, e202100754
DOI: 10.1002/ejic.202100754
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Arnau Call, Marco Cianfanelli, Pau Besalú-Sala, Giorgio Olivo, Andrea Palone, Laia Vicens, Xavi Ribas, JosepM. Luis, Massimo Bietti, Miquel Costas
Carboxylic Acid Directed γ-Lactonization of Unactivated Primary C–H Bonds Catalyzed by Mn Complexes: Application to Stereoselective Natural Product Diversification
J. Am. Chem. Soc., 2022, 144, 19542-19558
DOI: 10.1021/jacs.2c08620
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Marco Galeotti, Laia Vicens, Michela Salamone, Miquel Costas, Massimo Bietti
Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp³ )–H Functionalization via Radical and Cationic Intermediates
J. Am. Chem. Soc., 2022, 144, 7391-7401
DOI: 10.1021/jacs.2c01466
Keywords: High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Silvia D’Agostini, Konstantin G. Kottrup, Carla Casadevall, Ilaria Gamba, Valeria Dantignana, Alberto Bucci, Miquel Costas, Julio Lloret-Fillol, Dennis G.H. Hetterscheid
Electrocatalytic Water Oxidation with α-[Fe(mcp)(OTf)₂ ] and Analogues
ACS Catal., 2021, 11, 2583-2595
DOI: 10.1021/acscatal.0c05439
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Eduard Masferrer-Rius, Margarida Borrell, Martin Lutz, Miquel Costas, RobertusJ.M. Klein Gebbink
Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes
Adv. Synth. Catal., 2021, 363, 3783-3795
DOI: 10.1002/adsc.202001590
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis