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Results: 74

Arnau Call, Andrea Palone, JordanP. Liles, Natalie P. Romer, Jacquelyne A. Read, JosepM. Luis, Matthew S. Sigman, Massimo Bietti, Miquel Costas
Understanding Catalytic Enantioselective C–H Bond Oxidation at Nonactivated Methylenes Through Predictive Statistical Modeling Analysis
ACS Catal., 2025, 15, 2110-2123
DOI: 10.1021/acscatal.4c05659
OpenAccess: Link
Keywords: Homogeneous catalysis, Oxidation, Predictive Chemistry, Reaction mechanisms, Regioselectivite functionalization

Nabhendu Pal, Jin Xiong, Mehmet Jahja, Sami Mahri, VictorG. Young, Yisong Guo, Marcel Swart, Lawrence Que
A 5,000-fold increase in the HAT reactivity of a nonheme Fe^IV =O complex simply by replacing two pyridines of the pentadentate N4Py ligand with pyrazoles
Proc. Natl. Acad. Sci. U.S.A., 2025, 122, ASAP-
DOI: 10.1073/pnas.2414962122
OpenAccess: –
Keywords: Homogeneous catalysis, Oxidation, Reaction mechanisms, Spin states

Andrea Álvarez-Núñez, Rudraditya Sarkar, Valeria Dantignana, Jin Xiong, Yisong Guo, Josep M. Luis, Miquel Costas, Anna Company
Intramolecular C–H Oxidation in Iron(V)-oxo-carboxylato Species Relevant in the γ-Lactonization of Alkyl Carboxylic Acids
ACS Catal., 2024, 14, 14183-14194
DOI: 10.1021/acscatal.4c01258
OpenAccess: Link
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Regioselectivite functionalization

Àlex Díaz-Jiménez, Roger Monreal-Corona, Miquel Solà, Albert Poater, Anna Roglans, Anna Pla-Quintana
Synthesis of 1H -Isoindole-Containing Scaffolds Enabled by a Nitrile Trifunctionalization
ACS Catal., 2024, 14, 7381-7388
DOI: 10.1021/acscatal.4c00932
OpenAccess: Link
Keywords: Cycloaddition, Homogeneous catalysis, Organometallics, Reaction mechanisms, Regioselectivite functionalization

Agustí Lledó, Jordi Solà
The Intermolecular Pauson‐Khand Reaction: Applications, Challenges, and Opportunities
Adv Synth Catal, 2024, 366, 574-592
DOI: 10.1002/adsc.202301236
OpenAccess: Link
Keywords: Cycloaddition, Homogeneous catalysis, Ligand design, Organometallics, Reaction mechanisms

Cristina Castanyer, Albert Artigas, Miquel Solà, Anna Pla-Quintana, Anna Roglans
On the Functionalization of C₆₀ with Vinylallenes Generatedin situ by Rhodium Catalysis
Adv Synth Catal, 2024, [], ASAP-
DOI: 10.1002/adsc.202401163
OpenAccess: Link
Keywords: Cycloaddition, Homogeneous catalysis, Organometallics, Reaction mechanisms, Regioselectivite functionalization

Almudena Inchausti, Rosa Mollfulleda, Marcel Swart, Josefina Perles, Santiago Herrero, ValentínG. Baonza, Mercedes Taravillo, Álvaro Lobato
Torsion Effects Beyond the δ Bond and the Role of π Metal‐Ligand Interactions
Advanced Science, 2024, 11, 2401293
DOI: 10.1002/advs.202401293
OpenAccess: Link
Keywords: Chemical bonding, Homogeneous catalysis, Spectroscopy

Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano, Giorgio Olivo
Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation
Angew Chem Int Ed, 2024, 63, e202401694
DOI: 10.1002/anie.202401694
OpenAccess: Link
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Regioselectivite functionalization, Supramolecular chemistry

Siu-Chung Chan, Andrea Palone, Massimo Bietti, Miquel Costas
tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds
Angew Chem Int Ed, 2024, 63, e202402858
DOI: 10.1002/anie.202402858
OpenAccess: Link
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Regioselectivite functionalization

Pau Font, Hugo Valdés, Xavi Ribas
Consolidation of the Oxidant‐Free Au(I)/Au(III) Catalysis Enabled by the Hemilabile Ligand Strategy
Angew Chem Int Ed, 2024, 63, e202405824
DOI: 10.1002/anie.202405824
OpenAccess: Link
Keywords: Cross-coupling reactions, Homogeneous catalysis, Ligand design, Organometallics