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Results: 46

Nikos Siakavaras, Arnau Call, Massimo Bietti, Miquel Costas
Desymmetrization of Malonic Monoesters and Malonic Acids via Enantioselective Catalytic C(sp³)─H Oxidation
Angew. Chem. Int. Ed., 2026, , 1433-7851
DOI: 10.1002/anie.1030779
OpenAccess: Link
Keywords: High-valent metal complexes, Homogeneous catalysis, Ligand design, Oxidation, Sustainable Catalysis

Margarida Borrell, Marco Galeotti, Laia Vicens, Tomer Mintz, Arnau Call, Doron Pappo, Miquel Costas
Installing Axial Chirality by Atroposelective C(sp³ )–H Bond Oxidation
J. Am. Chem. Soc., 2026, 148, 21080-21091
DOI: 10.1021/jacs.6c06123
OpenAccess: Link
Keywords: Homogeneous catalysis, Ligand design, Method development, Oxidation, Sustainable Catalysis

Najoua Choukairi Afailal, Siu-Chung Chan, Miquel Costas
Manganese‐Catalyzed Enantioselective Dearomative Epoxidation of Naphthalenes with Aqueous Hydrogen Peroxide
Angew Chem Int Ed, 2025, 64, e202504356
DOI: 10.1002/anie.202504356
OpenAccess: Link
Keywords: Aromaticity, High-valent metal complexes, Homogeneous catalysis, Oxidation, Sustainable Catalysis

Miquel Costas, Andrea Palone, Arnau Call, Aleria Garcia-Roca, Josep M. Luis, Matthew S. Sigman, Massimo Bietti, Cristina Nevado
Shaping of a Reactive Manganese Catalyst Enables Access to Polyfunctionalized Cyclohexanes via Enantioselective C(sp3)−H Bond Oxidation of 1,3‐meso Diethers
Angew Chem Int Ed, 2025, 64, e202507755
DOI: 10.1002/anie.202507755
OpenAccess: Link
Keywords: Homogeneous catalysis, Ligand design, Predictive Chemistry, Reaction mechanisms, Sustainable Catalysis

Anjana Rajeev, Sethuraman Muthuramalingam, VisvesvararPitchai Murugan, Miquel Costas, Prabha Vadivelu, Muniyandi Sankaralingam
Unveiling the Catalytic Activity of Nickel(II) Complexes of Pentadentate Ligands in Aromatic Oxidations
ChemCatChem, 2025, 17, e202401645
DOI: 10.1002/cctc.202401645
OpenAccess: –
Keywords: Homogeneous catalysis, Oxidation, Reaction mechanisms, Sustainable Catalysis

Àlex Díaz-Jiménez, Nil Insa-Carreras, Anna Roglans, Anna Pla-Quintana, Miquel Costas
Iron-Catalyzed Intermolecular N–H Insertion Using Acceptor–Acceptor Carbenes Derived from Iodonium Ylides
Org. Lett., 2025, 27, 7804-7809
DOI: 10.1021/acs.orglett.5c02000
OpenAccess: Link
Keywords: Homogeneous catalysis, Reaction mechanisms, Sustainable Catalysis

Najoua Choukairi Afailal, Margarida Borrell, Marco Cianfanelli, Miquel Costas
Dearomativesyn -Dihydroxylation of Naphthalenes with a Biomimetic Iron Catalyst
J. Am. Chem. Soc., 2024, 146, 240-249
DOI: 10.1021/jacs.3c08565
OpenAccess: Link
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Sustainable Catalysis

Andrea Palone, Massimo Bietti, Miquel Costas
Enzymatic and Bio-Inspired Enantioselective Oxidation of Non-Activated C(sp 3)–H Bonds
Synthesis, 2024, [], ASAP-
DOI: 10.1055/a-2403-0760
OpenAccess: –
Keywords: Biocatalysis, Homogeneous catalysis, Oxidation, Regioselectivite functionalization, Sustainable Catalysis

Johann B. Kasper, Laia Vicens, C.Maurits de Roo, Ronald Hage, Miquel Costas, Wesley R. Browne
Reversible Deactivation of Manganese Catalysts in Alkene Oxidation and H₂ O₂ Disproportionation
ACS Catal., 2023, 13, 6403-6415
DOI: 10.1021/acscatal.3c00866
OpenAccess: Link
Keywords: Homogeneous catalysis, Oxidation, Reaction mechanisms, Spectroscopy, Sustainable Catalysis

Johann B. Kasper, Pattama Saisaha, Maurits de Roo, Mitchell J. Groen, Laia Vicens, Margarida Borrell, Johannes W. de Boer, Ronald Hage, Miquel Costas, Wesley R. Browne
A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H₂ O₂ and a Mn(II)/Pyridin‐2‐Carboxylato Catalyst
ChemCatChem, 2023, 15, e202201072
DOI: 10.1002/cctc.202201072
OpenAccess: Link
Keywords: Catalysis, Oxidation, Reaction mechanisms, Spectroscopy, Sustainable Catalysis