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Results: 70

Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano, Giorgio Olivo
Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation
Angew Chem Int Ed, 2024, 63, ASAP-
DOI: 10.1002/anie.202401694
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Regioselectivite functionalization, Supramolecular chemistry

Siu-Chung Chan, Andrea Palone, Massimo Bietti, Miquel Costas
tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds
Angew Chem Int Ed, 2024, [], ASAP-
DOI: 10.1002/anie.202402858
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Regioselectivite functionalization

Najoua Choukairi Afailal, Margarida Borrell, Marco Cianfanelli, Miquel Costas
Dearomativesyn -Dihydroxylation of Naphthalenes with a Biomimetic Iron Catalyst
J. Am. Chem. Soc., 2024, 146, 240-249
DOI: 10.1021/jacs.3c08565
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Sustainable Catalysis

Marco Galeotti, Massimo Bietti, Miquel Costas
Catalyst and Medium Control over Rebound Pathways in Manganese-Catalyzed Methylenic C–H Bond Oxidation
J. Am. Chem. Soc., 2024, 146, 8904-8914
DOI: 10.1021/jacs.3c11555
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Regioselectivite functionalization

Donglin Diao, Anna Baidiuk, Leo Chaussy, Iago De Assis Modenez, Xavi Ribas, Marius Réglier, Vlad Martin-Diaconescu, Paola Nava, A.Jalila Simaan, Alexandre Martinez, Cédric Colomban
Light-Induced Reactivity Switch at O₂ –Activating Bioinspired Copper(I) Complexes
JACS Au, 2024, 4, 1966-1974
DOI: 10.1021/jacsau.4c00184
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Reaction mechanisms, Supramolecular chemistry

Bittu Chandra, Faiza Ahsan, Yuan Sheng, Marcel Swart, Lawrence Que
A tale of two topological isomers: Uptuning [Fe^IV (O)(Me₄ cyclam)]²⁺ for olefin epoxidation
Proc. Natl. Acad. Sci. U.S.A., 2024, 121, ASAP-
DOI: 10.1073/pnas.2319799121
Keywords: High-valent metal complexes, Homogeneous catalysis, Joint Exp-Comp, Oxidation, Reaction mechanisms

Johann B. Kasper, Laia Vicens, C.Maurits de Roo, Ronald Hage, Miquel Costas, Wesley R. Browne
Reversible Deactivation of Manganese Catalysts in Alkene Oxidation and H₂ O₂ Disproportionation
ACS Catal., 2023, 13, 6403-6415
DOI: 10.1021/acscatal.3c00866
Keywords: Homogeneous catalysis, Oxidation, Reaction mechanisms, Spectroscopy, Sustainable Catalysis

Gibu George, Albert Poater, Miquel Solà, Sergio Posada-Pérez
Unveiling Oxygen Evolution Reaction on LiCoO₂ Cathode: Insights for the Development of High‐Performance Aqueous Lithium‐ion Batteries
Batteries & Supercaps, 2023, [], ASAP-
DOI: 10.1002/batt.202300452
Keywords: Electron and energy transfer, Nanomaterials, Oxidation

Johann B. Kasper, Pattama Saisaha, Maurits de Roo, Mitchell J. Groen, Laia Vicens, Margarida Borrell, Johannes W. de Boer, Ronald Hage, Miquel Costas, Wesley R. Browne
A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H₂ O₂ and a Mn(II)/Pyridin‐2‐Carboxylato Catalyst
ChemCatChem, 2023, 15, e202201072
DOI: 10.1002/cctc.202201072
Keywords: Catalysis, Oxidation, Reaction mechanisms, Spectroscopy, Sustainable Catalysis

Kazuki Nakanishi, LeonardoI. Lugo-Fuentes, Jun Manabe, Ronghao Guo, Soichi Kikkawa, Seiji Yamazoe, Kenji Komaguchi, Shoko Kume, DariuszW. Szczepanik, Miquel Solà, J.OscarC. Jimenez-Halla, Sadafumi Nishihara, Kazuyuki Kubo, Yohsuke Yamamoto, Masaaki Nakamoto, Tsutomu Mizuta, Rong Shang
Redox Activity of IrIII Complexes with Multidentate Ligands Based on Dipyrido‐annulated N‐Heterocyclic Carbenes: Access to High Valent and High Spin State with Carbon Donors
Chemistry A European J, 2023, [], e202302303
DOI: 10.1002/chem.202302303
Keywords: High-valent metal complexes, Organometallics, Oxidation, Spin states