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Results: 69

Kazuki Nakanishi, LeonardoI. Lugo-Fuentes, Jun Manabe, Ronghao Guo, Soichi Kikkawa, Seiji Yamazoe, Kenji Komaguchi, Shoko Kume, DariuszW. Szczepanik, Miquel Solà, J.OscarC. Jimenez-Halla, Sadafumi Nishihara, Kazuyuki Kubo, Yohsuke Yamamoto, Masaaki Nakamoto, Tsutomu Mizuta, Rong Shang
Redox Activity of IrIII Complexes with Multidentate Ligands Based on Dipyrido‐annulated N‐Heterocyclic Carbenes: Access to High Valent and High Spin State with Carbon Donors
Chemistry A European J, 2023, 29, e202302303
DOI: 10.1002/chem.202302303
OpenAccess: –
Keywords: High-valent metal complexes, Organometallics, Oxidation, Spin states

Mainak Mitra, Alexander Brinkmeier, Yong Li, Margarida Borrell, Arnau Call, Julio Lloret Fillol, MichaelG. Richmond, Miquel Costas, Ebbe Nordlander
An investigation of steric influence on the reactivity of FeV (O)(OH) tautomers in stereospecific C–H hydroxylation
Dalton Trans., 2023, 52, 3596-3609
DOI: 10.1039/D2DT00725H
OpenAccess: Link
Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable Catalysis

Maria Drosou, Gerard Comas-Vilà, Frank Neese, Pedro Salvador, Dimitrios A. Pantazis
Does Serial Femtosecond Crystallography Depict State-Specific Catalytic Intermediates of the Oxygen-Evolving Complex?
J. Am. Chem. Soc., 2023, 145, 10604-10621
DOI: 10.1021/jacs.3c00489
OpenAccess: Link
Keywords: Chemical bonding, High-valent metal complexes, Real-space analysis, Spectroscopy

Arnau Call, Giorgio Capocasa, Andrea Palone, Laia Vicens, Eric Aparicio, Najoua Choukairi Afailal, Nikos Siakavaras, MariaEugènia López Saló, Massimo Bietti, Miquel Costas
Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondaryγ -C–H Bonds
J. Am. Chem. Soc., 2023, 145, 18094-18103
DOI: 10.1021/jacs.3c06231
OpenAccess: Link
Keywords: High-valent metal complexes, Homogeneous catalysis, Oxidation, Regioselectivite functionalization, Sustainable Catalysis

Frederico F. Martins, Marcel Swart
Electronic properties and redox chemistry of N-confused metalloporphyrins
J. Porphyrins Phthalocyanines, 2023, [], A-J
DOI: 10.1142/S1088424623500918
OpenAccess: Link
Keywords: Excited states, High-valent metal complexes, Spectroscopy, Spin states

Pau Font, Nikolaos V. Tzouras, Argyro T. Papastavrou, Georgios C. Vougioukalakis, Xavi Ribas
Novel NHC-Based Au(I) Complexes as Precursors of Highly Pure Au(0) Nuggets under Oxidative Conditions
Molecules, 2023, 28, 2302-
DOI: 10.3390/molecules28052302
OpenAccess: Link
Keywords: Catalysis, High-valent metal complexes, Organometallics, Reaction mechanisms

Valeria Dantignana, M. Carmen Pérez-Segura, Pau Besalú-Sala, Estefanía Delgado-Pinar, Álvaro Martínez-Camarena, Joan Serrano-Plana, Andrea Álvarez-Núñez, CarmenE. Castillo, Enrique García-España, Josep M. Luis, ManuelG. Basallote, Miquel Costas, Anna Company
Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity
Angew Chem Int Ed, 2022, 62, e202211361
DOI: 10.1002/anie.202211361
OpenAccess: Link
Keywords: High-valent metal complexes, Oxidation, Reaction mechanisms

Charafa Souilah, Sergio A.V. Jannuzzi, Derya Demirbas, Sergei Ivlev, Marcel Swart, Serena DeBeer, Alicia Casitas
Synthesis of FeIII and FeIV Cyanide Complexes Using Hypervalent Iodine Reagents as Cyano‐Transfer One‐Electron Oxidants
Angew. Chem. Int. Ed., 2022, 61, e202201699
DOI: 10.1002/anie.202201699
OpenAccess: Link
Keywords: Catalysis, Computational chemistry, High-valent metal complexes, Organometallics, Homogeneous catalysis

A. Sevillano Chapartegui, M. Rodriguez, M. Costas, X. Ribas, S. Ruiz-Martinez, T. Puig
38P New tetraamine compounds targeting BCSCs from chemoresistant basal-like TNBC subtypes
Annals of Oncology, 2022, 33, S17-
DOI: 10.1016/j.annonc.2022.01.047
OpenAccess: –
Keywords: High-valent metal complexes

Pau Font, Hugo Valdés, Gregorio Guisado-Barrios, Xavi Ribas
Hemilabile MIC^N ligands allow oxidant-free Au(i )/Au(iii ) arylation-lactonization of γ-alkenoic acids
Chem. Sci., 2022, 13, 9351-9360
DOI: 10.1039/D2SC01966C
OpenAccess: Link
Keywords: Catalysis, Cross-coupling reactions, High-valent metal complexes, Organometallics

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