The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic Csp3-H bond has been Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp3)-H Bond Insertion
Reactions that enable selective functionalization of strong aliphatic C-H bonds open new synthetic paths to rapidly increase molecular Carboxylic Acid Directed gamma-Lactonization of Unactivated Primary C-H Bonds Catalyzed by Mn Complexes: Application to Stereoselective Natural Product Diversification
Two oxoiron(IV) isomers ( R2a and R2b) of general formula [FeIV(O)(RPyNMe3)(CH3CN)]2+ are obtained by reaction of their iron(II) Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity
Last Thursday took place the Autumn edition of the IQCC Forum, a quarterly meeting-place where high-quality science is IQCC Forum: Autumn edition 2022
Next Friday will be the defense of the doctoral thesis of Ernest Ubasart Clar , titled “Synthesis and PhD defense Ernest Ubasart
Methods for regioselective N-methylation and -alkylation of unsaturated heterocycles with “off the shelf” reagents are highly sought-after. This Selective Biocatalytic N-Methylation of Unsaturated Heterocycles
In this research article, we describe a 4H+/4e- electron-coupled-proton buffer (ECPB) based on Cu and a redox-active ligand. A 4H+/4e- Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex
The aerobic oxidation of alkenes to carbonyls is an important and challenging transformation in synthesis. Recently, a new Enzymatic Control over Reactive Intermediates Enables Direct Oxidation of Alkenes to Carbonyls by a P450 Iron-Oxo Species
Last week (Aug 28th to Sept 2nd 2022) took place the 19th International Conference on Density Functional Theory Gerard Comas wins poster prize at the 19th International Conference on DFT in Brussels
In this work, we propose specific electrolyte formulations for Na-ion batteries comprising linear and cyclic ether-based solvents and Extending low-temperature operation of sodium metal batteries