Month: September 2017

Highly reactive oxoiron(IV) with bioinspired N3O ligand

The sluggish oxidants, [FeIV(O)(TMC)(CH3CN)] 2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and [FeIV(O)(d12-TMCN)(OTf)] + (3d; d12-TMCN = 1,4,7,11-tetra-d3-methyl-1,4,7,11-tetraazacyclotetradecane), are transformed into Highly reactive oxoiron(IV) with bioinspired N3O ligand

Continue Reading