Two metastable NiIII complexes, [NiIII(OAc)(L)] and [NiIII(ONO2)(L)] (L = N,N’-(2,6-dimethylphenyl)-2,6-pyridinedicarboxamidate, OAc = acetate), were prepared, adding to the Tuning the reactivity of terminal nickel(III)-oxygen adducts
One of the Plenary Speakers of the Girona Seminar, Prof. Borovik (UC Irvine), asked Prof. Swart for his Girona Seminar Offspring: Where does the proton goá
Terminal high-valent metal-oxygen species are key reaction intermediates in the catalytic cycle of both enzymes (e.g., oxygenases) and Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Ni-O Species