Publications

Advanced filters

Author/s: Enter the author's full name or part of their name

Keyword: Filter by specific keyword

2019

Highly enantioselective epoxidation of olefins by H2O2 catalyzed by a non-heme Fe(ii) catalyst of a chiral tetradentate ligand

Authors: Mainak Mitra, Olaf Cusso, Satish S. Bhat, Mingzhe Sun, Marco Cianfanelli, Miquel Costas, Ebbe Nordlander

Dalton Transactions, 2019, 48, 18, 6123-6131

DOI: 10.1039/c8dt04449j

Keywords: Catalysis, High-valent metal complexes, Oxidation, Sustainable catalysis

Octahedral iron(iv)–tosylimido complexes exhibiting single electron-oxidation reactivity

Authors: Gerard Sabenya, Ilaria Gamba, Laura Gómez, Martin Clémancey, Jonathan R. Frisch, Eric J. Klinker, Geneviève Blondin, Stéphane Torelli, Lawrence Que, Vlad Martin-Diaconescu, Jean-Marc Latour, Julio Lloret-Fillol, Miquel Costas

Chemical Science, 2019, 10, 41, 9513-9529

DOI: 10.1039/c9sc02526j

Keywords: Catalysis, Density Functional Theory, High-valent metal complexes, Reaction mechanisms, Spectroscopy

2018

The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C–H Bond Oxygenation

Authors: Michela Milan, Michela Salamone, Miquel Costas, Massimo Bietti

Accounts of Chemical Research, 2018, 51, 9, 1984-1995

DOI: 10.1021/acs.accounts.8b00231

Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable catalysis

Aliphatic C–H Bond Oxidation with Hydrogen Peroxide Catalyzed by Manganese Complexes: Directing Selectivity through Torsional Effects

Authors: Michela Milan, Massimo Bietti, Miquel Costas

Organic Letters, 2018, 20, 9, 2720-2723

DOI: 10.1021/acs.orglett.8b00929

Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable catalysis

Understanding the Catalase-Like Activity of a Bioinspired Manganese(II) Complex with a Pentadentate NSNSN Ligand Framework. A Computational Insight into the Mechanism

Authors: Maria Letizia Merlini, George J. P. Britovsek, Marcel Swart, Paola Belanzoni

ACS Catalysis, 2018, 8, 4, 2944-2958

DOI: 10.1021/acscatal.7b03559

Keywords: Catalysis, Computational chemistry, Density Functional Theory, High-valent metal complexes, Homogeneous catalysis

A Deep Cavitand Receptor Functionalized with Fe(II) and Mn(II) Aminopyridine Complexes for Bioinspired Oxidation Catalysis

Authors: Diego Vidal, Miquel Costas, Agustí Lledó

ACS Catalysis, 2018, 8, 4, 3667-3672

DOI: 10.1021/acscatal.7b04426

Keywords: Catalysis, Confined space, High-valent metal complexes, Oxidation, Supramolecular chemistry

Detection of Indistinct Fe−N Stretching Bands in Iron(V) Nitrides by Photodissociation Spectroscopy

Authors: Erik Andris, Rafael Navrátil, Juraj Jašík, Gerard Sabenya, Miquel Costas, Martin Srnec, Jana Roithová

Chemistry – A European Journal, 2018, 24, 20, 5078-5081

DOI: 10.1002/chem.201705307

Keywords: Density Functional Theory, High-valent metal complexes, Reaction mechanisms, Spectroscopy

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV–Oxo Intermediate

Authors: Ruixi Fan, Joan Serrano-Plana, Williamson N. Oloo, Apparao Draksharapu, Estefanía Delgado-Pinar, Anna Company, Vlad Martin-Diaconescu, Margarida Borrell, Julio Lloret-Fillol, Enrique García-España, Yisong Guo, Emile L. Bominaar, Lawrence Que, Miquel Costas, Eckard Münck

Journal of the American Chemical Society, 2018, 140, 11, 3916-3928

DOI: 10.1021/jacs.7b11400

Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Spectroscopy

Effective Tetradentate Compound Complexes against Leishmania spp. that Act on Critical Enzymatic Pathways of These Parasites

Authors: Kristína Urbanová, Inmaculada Ramírez-Macías, Rubén Martín-Escolano, María José Rosales, Olaf Cussó, Joan Serrano, Anna Company, Manuel Sánchez-Moreno, Miquel Costas, Xavi Ribas, Clotilde Marín

Molecules, 2018, 24, 1, 134

DOI: 10.3390/molecules24010134

Keywords: Catalysis, High-valent metal complexes, Metalloproteins, Oxidation

H2O2 Oxidation by FeIII–OOH Intermediates and Its Effect on Catalytic Efficiency

Authors: Juan Chen, Apparao Draksharapu, Davide Angelone, Duenpen Unjaroen, Sandeep K. Padamati, Ronald Hage, Marcel Swart, Carole Duboc, Wesley R. Browne

ACS Catalysis, 2018, 8, 10, 9665-9674

DOI: 10.1021/acscatal.8b02326

Keywords: Catalysis, Density Functional Theory, High-valent metal complexes, Homogeneous catalysis, Reaction mechanisms

Trapping Iron(III)–Oxo Species at the Boundary of the “Oxo Wall”: Insights into the Nature of the Fe(III)–O Bond

Authors: Erik Andris, Rafael Navrátil, Juraj Jašík, Mayank Puri, Miquel Costas, Lawrence Que, Jana Roithová

Journal of the American Chemical Society, 2018, 140, 43, 14391-14400

DOI: 10.1021/jacs.8b08950

Keywords: Chemical bonding, High-valent metal complexes, Metalloproteins, Oxidation, Reaction mechanisms

Indirect evidence for a NiIII–oxyl oxidant in the reaction of a NiII complex with peracid

Authors: Paolo Pirovano, Abigail R. Berry, Marcel Swart, Aidan R. McDonald

Dalton Transactions, 2018, 47, 1, 246-250

DOI: 10.1039/c7dt03316h

Keywords: Catalysis, Computational chemistry, High-valent metal complexes, Homogeneous catalysis, Reaction mechanisms

Biologically inspired oxidation catalysis using metallopeptides

Authors: Laia Vicens, Miquel Costas

Dalton Transactions, 2018, 47, 6, 1755-1763

DOI: 10.1039/c7dt03657d

Keywords: Catalysis, High-valent metal complexes, Oxidation, Supramolecular chemistry, Sustainable catalysis

Enantioselective aliphatic C–H bond oxidation catalyzed by bioinspired complexes

Authors: Michela Milan, Massimo Bietti, Miquel Costas

Chemical Communications, 2018, 54, 69, 9559-9570

DOI: 10.1039/c8cc03165g

Keywords: Catalysis, High-valent metal complexes, Oxidation, Reaction mechanisms, Sustainable catalysis

2017

Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex

Authors: Sandeep K. Padamati, Davide Angelone, Apparao Draksharapu, Gloria Primi, David J. Martin, Moniek Tromp, Marcel Swart, Wesley R. Browne

Journal of the American Chemical Society, 2017, 139, 25, 8718-8724

DOI: 10.1021/jacs.7b04158

Keywords: Catalysis, Computational chemistry, Density Functional Theory, High-valent metal complexes, Homogeneous catalysis

Supramolecular Recognition Allows Remote, Site‐Selective C−H Oxidation of Methylenic Sites in Linear Amines

Authors: Giorgio Olivo, Giulio Farinelli, Alessia Barbieri, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas

Angewandte Chemie International Edition, 2017, 56, 51, 16347-16351

DOI: 10.1002/anie.201709280

Keywords: Catalysis, High-valent metal complexes, Oxidation, Supramolecular chemistry, Sustainable catalysis

Spin‐State‐Controlled Photodissociation of Iron(III) Azide to an Iron(V) Nitride Complex

Authors: Erik Andris, Rafael Navrátil, Juraj Jašík, Gerard Sabenya, Miquel Costas, Martin Srnec, Jana Roithová

Angewandte Chemie International Edition, 2017, 56, 45, 14057-14060

DOI: 10.1002/anie.201707420

Keywords: Excited states, High-valent metal complexes, Spectroscopy

A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand

Authors: Inés Monte Pérez, Xenia Engelmann, Yong‐Min Lee, Mi Yoo, Elumalai Kumaran, Erik R. Farquhar, Eckhard Bill, Jason England, Wonwoo Nam, Marcel Swart, Kallol Ray

Angewandte Chemie International Edition, 2017, 56, 46, 14384-14388

DOI: 10.1002/anie.201707872

Keywords: Catalysis, Computational chemistry, High-valent metal complexes, Homogeneous catalysis, Reaction mechanisms

Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2

Authors: Teresa Corona, Sandeep K. Padamati, Ferran Acuña-Parés, Carole Duboc, Wesley R. Browne, Anna Company

Chem. Commun., 2017, 53, 86, 11782-11785

DOI: 10.1039/c7cc05904c

Keywords: Density Functional Theory, High-valent metal complexes, Oxidation, Reaction mechanisms, Spectroscopy

« Previous 1 2 34