Terminal oxo complexes of late transition metals are frequently proposed reactive intermediates. However, they are scarcely known beyond The oxo wall revisited: Cobalt oxo vs. cobalt oxyl

The constant environmental pollution due to different toxic products derived from oil-based industries is nowadays a worldwide problem. Fe(V) intermediate mimics enzymes in the gas phase

Today, Miquel Costas and co-workers reported in JACS on the trapping of Fe(III)=oxo species. Terminal non-heme iron(IV)-oxo compounds Trapping Iron(III)-Oxo species at the boundary of the “Oxo-Wall”

Aliphatic C-H bond functionalization is at the frontline of research because it can provide straightforward access to simplified The quest for selectivity in hydrogen atom transfer reactions